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What is the lithium Intercalation Mechanism of Graphite?

Since the beginning of this year, people around the world have felt the pressure of rising prices. Not only the rise in oil prices but also different industries have seen soaring prices. According to the latest data, from August 2021 to the present, the inflation rate in the United States has risen for 6 consecutive months, and this data has soared from the previous 5.3% to 7.9% today. Inflation in the United States, the global Many countries have been affected.
According to experts' forecasts, the inflation rate in the United States may exceed 10% this year, which will face the danger of collapse, which has a great impact on global inflation, including Graphite.

Graphite has good conductivity, high crystallinity, and a well-layered structure. It is very suitable for repeated intercalation and deintercalation of lithium ions. It is currently the most widely used and most mature negative electrode material. After lithium ions are intercalated between the graphite layers, a lithium intercalation compound LixC6 (0≤x≤1) is formed, and the theoretical capacity can reach 372mAh/g (x=1). The reaction formula is: xLi++6C+xe-→LixC6

Lithium-ion intercalation changes the stacking mode between graphite layers from ABAB to AAAA.

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Graphite modification treatment

Since the graphite interlayer spacing (d≤0.34nm) is smaller than the crystal plane interlayer spacing (0.37nm) of the graphite lithium intercalation compound LixC6, the graphite layer spacing changes during the charging and discharging process, which is easy to cause the graphite layer to peel off, pulverize, and also occur. Lithium ions and organic solvent molecules co-intercalate into the graphite layer, and the organic solvent decomposes, affecting the battery cycle performance.

Through graphite modification, such as oxidation on the surface of graphite and coating of polymer pyrolytic carbon, composite graphite with a core-shell structure can be formed, improving the charge and discharge performance of graphite and increasing the specific capacity.

Other anode materials

At present, graphite is the mainstream commercial lithium battery negative electrode material. Its theoretical gram capacity is 372mAh/g. The graphite negative electrode material with better performance on the market can reach 360mAh/g, and the gram capacity gradually tends to the limit value. Although graphite as a negative electrode material has disadvantages such as low gram capacity and cycle deviation, because of the high-cost performance of graphite-based negative electrode materials, it will not be replaced by new materials immediately. The specific reasons are as follows:

1. The new anode material technology is immature, and it will take a long time for performance improvement;

2. The price of new anode materials is higher, and the price advantage of graphite anodes is obvious;

3. The negative electrode material needs to be used in combination with the positive electrode material, electrolyte, etc., and the specific capacity of the current positive electrode material is generally low.

High-quality graphite supplier

Luoyang Moon & Star New Energy Technology Co., LTD, founded on October 17, 2008, is a high-tech enterprise committed to developing, producing, processing, selling, and technical services of lithium-ion battery anode materials. After more than 10 years of development, the company has gradually developed into a diversified product structure with natural graphite, artificial graphite, composite graphite, intermediate phase, and other negative materials (silicon-carbon materials, etc.). The products are widely used in high-end lithium-ion digital power and energy storage batteries. If you are looking for Lithium battery anode material, click on the needed products and send us an inquiry:sales@graphite-corp.com

 


Since the beginning of this year, China's macro policies have made continuous efforts to stabilize economic growth. America and Europe are raising interest rates to control inflation. On March the European Central Bank left its three key interest rates unchanged and began to scale back its asset-purchase programme. Then the Federal Reserve raised the target range of the federal funds rate by 25 basis points to 0.25%-0.5%. The accelerated tightening of monetary policies in the US and Europe pushed capital back to the US and increased interest rates, which will definitely increase the risk of RMB depreciation and capital outflow. The price and market of the Graphite will also be affected, resulting in a range of fluctuations. You are welcome to contact us for the latest quotation of Graphite.

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